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Celtic will face holders Real Madrid in the Champions League group stage as Rangers take on Liverpool.
The Parkhead club will also play RB Leipzig and Shakhtar Donetsk of Ukraine in group F.
Giovanni van Bronckhorst’s Rangers will welcome Ajax of the Netherlands and Serie A’s Napoli to Ibrox along with Jurgen Klopp’s side.
Celtic qualified as Scottish champions while Rangers defeated PSV Eindhoven in the play-offs.
It is the first time in 15 years two Scottish teams have reached the group stage of Europe’s top competition, with Rangers making a return after a 12-year absence.
Glasgow rivals Celtic last reached the Champions League in 2017-18.
More to follow.